（新课程）高一KEYLEARNINGENGLISH 6 关综合能力提升(上接第3版)have had to strike onekey at a time可知i，作者看出time with friendly-minded people but have trouble 3. just then 4. givc a lcsson toDoug的状态应当非常差，他一定是不舒服地一opening theirmouths可知，沉默读书俱乐部会特6. close by5. dressed up个键一个键地敲击，艰难地写信。别吸引不擅长交谈的人们。阅读理解11.A。推理判断题。本文主要介绍沉默读书语篇类型是说明文，主题语境是人与社会之12.B。根据空后内容和下文的r'dneverknow俱乐部的起源、发展状况以及独特的运作方式。历史、社会与文化。随着爱尔兰到悉尼的移民的what he13to write可知，信件突然结束了。增多，爱尔兰中餐在悉尼开始流行，特别是其招13.C。根据上文老人写给作者的信突然结束由此可知，本文的主要目的是介绍一种新型的读了可知，作者遗憾不知道老人打算写什么。书俱乐部。牌香料包。1.A。细节理解题。根据第二段Riona Magce14.A。根据上文的Id never knowwhat heD语篇类型是说明文，主题语境是人与自然之说的话...but it's something you want when you're13_towrite可知，重要的不仅仅是信件的内容。环境保护。科学家经研究发现与100年前相比，许miles awayfrom home和第三段ColinFassnidge说15.D。根据文章的第一段可推知，重要的是，在如今忙碌的世界写信表明写信人为了做一件多鸟类现在筑巢和产卵的时间都提前了将近一的话We eat it and we smile because it reminds usof beingbackinIreland可知，二人关于香料包的特别的事情付出了努力。个月，这最有可能是因为气候变化导致的。共识就是，它缓解了他们这些爱尔兰移居者的思12.D。推理判断题。根据第一段的内容可推语法填空知，研究发现与近一个世纪前相比，许多鸟类物1.a 2. powerful3. With乡之情。2. C。细节理解题。根据第三段的Demand5. where种现在把筑巢和产卵时间提前了近一个月。研究4. were forced6. terriblyfor Irish Chinese food has greatly incrcased since7. crying 8. amazed人员通过对比博物馆收藏的鸟蛋信息和最近的9. directions2023, when more than 21,000 working holiday鸟类行为观察结果发现，芝加哥约三分之一的鸟10. confidence类物种把产卵时间提前了约25天。文章认为，引visas were given to Irish residents aged under 35可Assignment 12知，随着澳大利亚为更多的35岁以下的爱尔兰居起这一变化的原因很可能是气候变化。因此，研综合测试(二)民发放工作假期签证，当地对爱尔兰中餐的需求阅读究的主要内容是分析气候变化对鸟类筑巢和产就大大增加。由此可见，爱尔兰中餐在悉尼流行第一节卵时间的影响。的主要原因是很多年轻的爱尔兰移居者的到来。13.B。细节理解题。根据第二段内容可知，A3.D。推理判断题。根据第五段的内容可知，语篇类型是应用文，主题语境是人与社会之Whelan明确提到了研究者如何在研究区域内寻作为TheTaphouse的主厨，SamNg从未听说过香历史、社会与文化。本文介绍了一趟游船之旅。找活跃的鸟巢，一旦发现了一个巢，研究者就仔料包，直到开始和餐饮总监PatrickFriesen一起细地确定它的阶段，再对其进行定期回访。也就1:C。细节理解题。根据About the activity部研究爱尔兰中餐的起源和发展轨迹。由此推知，分的Audio guide in Arabic, Chinese, English ..和是说，研究过程包括搜索活跃的鸟巢。在TheTaphouse推出香料包之前，他们了解了香Included部分的Headphone audio tour可知，票价料包的起源。包含个人语音导览耳机。is stored along with handwritten notes about what4.C。标题归纳题。文章第一段点明了本文的bird it camefromandexactlywhatdayitwas2.D。细节理解题。根据Included部分的主旨,即爱尔兰中餐在悉尼颇受欢迎。collected可知，这此手写笔记中包含的信息包括90-minute cruise和Description部分的During the阅读填空 round-trip cruise可知，这趟游船之旅是一次90分每个蛋来自哪种鸟类,以及蛋被收集的确切日1-5 ACFED钟的往返行程。期。Assignment 113.A。推理判断题。通读全文可知，本文详细15.A。细节理解题。根据最后一段特别是最知识回顾·介绍了从金门大桥到旧金山一奥克兰海湾大桥后—句And the researchers point out that it could1. 1. emotional. 2. comparison 3.equally的一趟游船之旅，所以最有可能来自旅游宣传have aneffect onwhat food is accessible to birds可 4. graceful5. distance知，尽管温度只有几度的变化，这足以导致不同II. 1. through 2. out3. to的昆虫出现和植物开花时间的改变，这可能会影5.ofB 4. along 语篇类型是记叙文，主题语境是人与社会之响到鸟类能够获取的食物来源。 I. 1. all over the world社会服务与人际沟通。艺术家KeithHaring为爱第二节 2. prevent cancer from developing荷华州一所小学创作了一幅壁画。如今，学校将16-20 CEGFA 3. make out what they are saying要翻新，壁画被移至斯坦利艺术博物馆保存起语言运用4. It seems 来。这幅壁画体现了教育和艺术的力量。第一节5. no matter what challenges she faces4.B。词义猜测题。根据第二段的内容可知，语篇类型是记叙文，主题语境是人与自我之完形填空Haring认为这些学生有新创意和好的想象力，并做人与做事。一对夫妻因赶路而感到急躁，但在语篇类型是记叙文，主题语境是人与自我之且尊重他人。根据第三段的内容可知，这些学生收费站口，他们给一辆车让行。他们没想到的是，做人与做事。作者小时候曾经给不懂英语的曾祖认为Haring会分享新的观点并尊重他们的思想，那名司机为了表示感谢，为他们支付了过路费。母写信，渐渐便有了写信的惯。手写信件代表故这些学生与Haring有相同的感受。这名司机的感谢方式照亮了这对夫妻的一天。。着写信人愿意付出时间与精力，这在如今忙碌的5.D。推理判断题。根据第五段的“It's21.C。根据空后内容和下一句可知，妻子不世界中是一件特别的事情。leally unbelievable to me that the school actively得不停下来处理工作上的事情。1. C。根据下文的My friend mentioned he 22.D。根据上一句和空后内容可知，作者他organized a discussion about AIDS-mostly2 my handwritten note, saying it was special in们在出发前面临了一些麻烦。because of the students' contact with me," Haringtoday's busyworld可知，作者一直喜欢写信，所以们23.A。根据空前内容和下一句可知，作者他wrote to the school可知，Haring认为学校能主动他从没觉得写信有什么特别。组织这样的活动让他难以置信,可见他深受触们进人妻子的公司时，保安想要搜查他们的车，2.B。根据下文的saying it was special in作者反对这些程序。object有“不赞成；反对"之today's busy world可知,朋友对作者的手写便条动。6.C。细节理解题。根据倒数第二段的内容可意。表示赞赏。知，学校在进行校舍翻修之前，需要寻找一种方24.D。根据下文的I sat in the car outside可3.D。根据后文的故事内容可知，作者从小就式来保护这幅壁画，于是他们求助于斯坦利艺术知,作者的妻子独自走进大门,作者坐在车上,在开始写信，长大后依然写信，写信是作者的一种博物馆。外面等。惯。25.B。根据空后的looking at my watch7.B。推理判断题。Lessing在最后一段中主4. A。根据下文的I used an English-Spanish要阐述了这幅壁画的意义：Haring的壁画展现了because we had a three-hour drive ahead of us可知,dictionary towrite toher可知，因为作者的曾祖母教育的力量及艺术家在促进人们相互理解方面作者坐在车里不停地看表。不懂英语，所以作者不得不用词典翻译。26.C。作者和妻子出发去旅行，本来已经晚5.C。根据上文的Iused an English-Spanish的重要作用。这幅壁画既是一个支持艺术的团体了，但妻子还要去办公室处理一件事情，作者自的美好表达，也是一封艺术家给一个接纳自己的dictionary及下文的but I stuck to this可知，写信的己在外面等，他很烦躁。过程虽然困难，但作者还是坚持了下来。团体写的情书。27.C。根据上文的故事内容可知,这不是一C6.D。根据空后的of youthful ideas and语篇类型是说明文，主题语境是人与社会之个好的开始。characters可知，作者长大后和朋友们通信，这此历史、社会与文化。在读书俱乐部里，人们往往需28.B。根据下文的I always stayed in the left信件被存放在一个盒子里，它们是年轻时候的想要完成一定的读书任务，并且参与讨论，这可能lane in the past可推知，作者对路线很熟悉。法和性格的记录。会给人们带来心理上的压力。也许我们可以尝试29.A。根据下文的there were usually fewer7. A。根据下文的just as it was in his care for加人一个“沉默读书俱乐部”，以更放松的方式享cars there可知，作者通常选择左边车道是为了避herwhenshenolongerrecognizedhimbecaue受读书和人际交往的快乐。免在过路收费亭排队，避免交通拥堵。dementia可知，道格对妻子的爱意在他的信中显8.D。推理判断题。根据第二段的They liked30.C。根据空前的Still可推知，作者成功挤而易见，现在，妻子认不出他了，他依然在她身边the friendliness but not the anxiousness caused进了右侧的车道。照看她，充满爱意。by tasks like finishing the book on time可知，31.A。根据下两句可知,作者注意到了左边8.B。根据空后的mostlythroughletters可知，Guinevere和Laura认为在普通的读书俱乐部里要车道的一名女司机。作者和老人主要通过信件保持联系。完成各种任务，是很令人紧张的。32.D。根据空后的as car after car passed her9.D。根据空后的alreadyknowing the9.B。细节理解题。根据第三段的...there's可知，女司机无法加入右侧车道，只能原地等待，message but hoping Iwaswrong可知，作者一直和 no assigned reading—members bring whatever所以作者让这辆车进来了。sit有“do nothing"之老人通信，但突然收到了来自他儿子的信件，作they'd like toreador guided discussion以及Once者的心情沉重，猜到了信件中的内容，但仍然希意。33. D。根据上文的Finally, I came by and letthe hour is up, members could choose to chat about望自己猜错了。her in和空后内容可知，作者前面的车辆是他允10.B。根据上文的In going through my dad'sthe books or any other things. They can also justthings可知，老人的儿子在整理遗物时发现了这continuereadingquietly可知，沉默读书俱乐部为许插队的那辆车。34.B。根据上文作者的心情变得糟糕和下文成员们提供了很大的活动自由。封信。10.C。细节理解题。根据第四段的The space的We spent therest of our driveingood chcer可知11. A。根据空前的I could see that Doug's那名女司机的举动让作者他们的情绪变好了。snu ay pue 'adi on u pny sumpuy Ayeus is most attractive to people who want to spend (下转第5版)

■ D.admired219876543210)49.A.createdB.collectedC.delivered接上页B.owedC.valuedD.stolen)50.A.lent第二节（满分25分）)51.A.alarming B.availableC.new D.special选择题阅读下面材料，根据其内容和所给段落开头语续写两段，使之构成一篇完整的短文。)52.A.message B.rankC.greetingD.plan答题栏A group of poor people live in a village of Africa. The people there relied on corn farming()53.A.false B.realC.beautiful D.legal(for their livelihood. However, the harsh natural conditions often resulted in poor harvests.D.fantasy)54.A.popularityB.requestC.quality41（Droughts were the biggest challenge, while sudden downpours during the rainy season wouldC.MoreoverB.ThereforeD.Instead55.A.Otherwise(flood the fields. Despite these difficulties, there was a young boy in the village named Steven(共10小题；每小题1.5分，满分15分)who had a deep love for science. He dreamed of using knowledge to change the fate of his阅读下面短文,在空白处填入1个适当的单词或括号内单词的正确形式。43community.56(create） by Lillian Hopps, In the center of Reykjavik, Iceland, stands a museum From a young age, the boy was fascinated by the wonders of science. He spent his days exploring the world around him, eager to uncover its mysteries. While other children played in44 Chinese heritage, Lillian began her journey to learn about China in the 1990s, a time57the fields, he could be found conducting “experiments"” and thinking about his future under the45 she deeply engaged herselfin exploring China's rich culture. Her passion transformed her homeshade of a tree. He wanted to develop a dam to store rainwater and then pump(用泵抽运） the 58 (eventual) led to the establishment of a into a place filled with Chinese artifacts, which _water from the dam to water the corn when there would be a drought. But to build the dam was46museum in Reykjavik.a big problem. 59(house) an extensive collection of cultural relics, from ancient47The museumHis passion for learning was undeniable, but his father, a traditionalist who valued hard60 contemporary art, displaying thousands of years of Chinese civilization.clothingwork above all else, did not understand or support his son's ambition at first. To him, the only48 r sa s i sre () pq so m s real way to help the family was through manual labor on the farm._(interact) activities like tea performances, caligraphy classes, andthrough highly62Despite his father's disapproval, Steven remained determined in his pursuit of knowledge.traditional medicine talks, promoting the Icelandic understanding of China's rich traditions. Steven believed that education held the key to a better future, not just for himself but for theLillian's museum, attracting thousands of visitors annually from around the world,5063 (recognize) by the Icelandic government in 2021 for its impact. As Marta Jonsdottir, arealized that perhaps there was more to life than working in the fields. With a heavy heart, he51director at Iceland's Ministry of Foreign Affairs, put it in an interview, “Lillian, with heremptied his savings to send Steven to school, hoping that one day his son would make his own64(link) between Iceland andenthusiasm and expertise, has developed diverse cultural 52dream come true.China. Her museum has not just enabled both peoples to better understand each other65 strengthened our relations."graduated with top honors from university. Armed with a wealth of knowledge and a burning1.501.501.5 057.1.5 056.58.59. desire to make a difference, he returned to his village with a mission in mind.5461.62.1.5063.1.5 0注意：60.551.续写词数应为150左右；1.5 065.1.5 0642.请按如下格式在相应位置作答。写作(共两节，满分40分)第四部分Upon returning to the village, Steven immediately started to solve the problem.1514131211109 876543210第一节（满分15分）假定你是李华,在暑假参与了一次社区志愿者服务活动。请你给英国朋友 Frank 写封邮件分享这次经历，内容包括：1.你做的工作；2.你的收获。注意：After learning about the project, all the villagers joined in the construction of the dam.1.写作词数应为 80 左右；2.请按如下格式在相应位置作答。Dear Frank,I hope this letter finds you well.Best regards,Li Hua英语·专题卷（六）7/8页英语·专题卷(六）8/8页

■ D.admired219876543210)49.A.createdB.collectedC.delivered接上页B.owedC.valuedD.stolen)50.A.lent第二节（满分25分）)51.A.alarming B.availableC.new D.special选择题阅读下面材料，根据其内容和所给段落开头语续写两段，使之构成一篇完整的短文。)52.A.message B.rankC.greetingD.plan答题栏A group of poor people live in a village of Africa. The people there relied on corn farming()53.A.false B.realC.beautiful D.legal(for their livelihood. However, the harsh natural conditions often resulted in poor harvests.D.fantasy)54.A.popularityB.requestC.quality41（Droughts were the biggest challenge, while sudden downpours during the rainy season wouldC.MoreoverB.ThereforeD.Instead55.A.Otherwise(flood the fields. Despite these difficulties, there was a young boy in the village named Steven(共10小题；每小题1.5分，满分15分)who had a deep love for science. He dreamed of using knowledge to change the fate of his阅读下面短文,在空白处填入1个适当的单词或括号内单词的正确形式。43community.56(create） by Lillian Hopps, In the center of Reykjavik, Iceland, stands a museum From a young age, the boy was fascinated by the wonders of science. He spent his days exploring the world around him, eager to uncover its mysteries. While other children played in44 Chinese heritage, Lillian began her journey to learn about China in the 1990s, a time57the fields, he could be found conducting “experiments"” and thinking about his future under the45 she deeply engaged herselfin exploring China's rich culture. Her passion transformed her homeshade of a tree. He wanted to develop a dam to store rainwater and then pump(用泵抽运） the 58 (eventual) led to the establishment of a into a place filled with Chinese artifacts, which _water from the dam to water the corn when there would be a drought. But to build the dam was46museum in Reykjavik.a big problem. 59(house) an extensive collection of cultural relics, from ancient47The museumHis passion for learning was undeniable, but his father, a traditionalist who valued hard60 contemporary art, displaying thousands of years of Chinese civilization.clothingwork above all else, did not understand or support his son's ambition at first. To him, the only48 r sa s i sre () pq so m s real way to help the family was through manual labor on the farm._(interact) activities like tea performances, caligraphy classes, andthrough highly62Despite his father's disapproval, Steven remained determined in his pursuit of knowledge.traditional medicine talks, promoting the Icelandic understanding of China's rich traditions. Steven believed that education held the key to a better future, not just for himself but for theLillian's museum, attracting thousands of visitors annually from around the world,5063 (recognize) by the Icelandic government in 2021 for its impact. As Marta Jonsdottir, arealized that perhaps there was more to life than working in the fields. With a heavy heart, he51director at Iceland's Ministry of Foreign Affairs, put it in an interview, “Lillian, with heremptied his savings to send Steven to school, hoping that one day his son would make his own64(link) between Iceland andenthusiasm and expertise, has developed diverse cultural 52dream come true.China. Her museum has not just enabled both peoples to better understand each other65 strengthened our relations."graduated with top honors from university. Armed with a wealth of knowledge and a burning1.501.501.5 057.1.5 056.58.59. desire to make a difference, he returned to his village with a mission in mind.5461.62.1.5063.1.5 0注意：60.551.续写词数应为150左右；1.5 065.1.5 0642.请按如下格式在相应位置作答。写作(共两节，满分40分)第四部分Upon returning to the village, Steven immediately started to solve the problem.1514131211109 876543210第一节（满分15分）假定你是李华,在暑假参与了一次社区志愿者服务活动。请你给英国朋友 Frank 写封邮件分享这次经历，内容包括：1.你做的工作；2.你的收获。注意：After learning about the project, all the villagers joined in the construction of the dam.1.写作词数应为 80 左右；2.请按如下格式在相应位置作答。Dear Frank,I hope this letter finds you well.Best regards,Li Hua英语·专题卷（六）7/8页英语·专题卷(六）8/8页

笔清楚that road ecologists are trying to do and need to do.28.What do the first two paragraphis mainly talk about?A. Animals' defense strategies.封 B. Cars' influence on wild animals.C. A crisis for worldwide biodiversity.D. Aninals* adaptation to ecological traps.29.Which can best explain the underlined word "luring" in paragraph 3?D. Dividing.C. Tricking.B. Terrifying. -A. Forcing.30.What aspect does the author mention about highways in paragraph 4?B. Their function as barriers.A. Their stream of traffic.线D. Their threat to animals.C. Their ecological environment.31.What is helpful for wild animals to find their new habitats? B. Turning to road ecologists.A. Building convenient passways.D. Creating moving fences.C. Increasing the biodiversity.DIf you've dealt with stiffness and pain in the recent past, you may have come across fascia25·G3DY(新高考）·英语(五)－WYB-心考-Y·51·

14.A。根据sothathecan thankher可知，Ghunta希望能再次见到这位老师。15.C。根据上文可知，在这位老师的指导下，Ghunta的阅读能力不断提高，最后不仅在小学以优异的成绩毕业，还上了大学并读了研，最后成了一名儿童书籍作家。因此，他应该很感激这位老师当时看到了他的潜力。第48期A版参考答案及部分解析A2版参考答案1. 1-4 DAADI1.1-5EAFGDIll.1.that/which2. developing3.Founded4.deepen5.expanded6.with7.satisfaction8.to explore9. previously10.and解析1.本文是说明文。文章介绍了自省的含义、重要性以及方法等。1.D。理解词汇。根据划线词后的by the end of the program，they told me that some of themosthelpfulpartswerethosefocusedonself-reflection可知，参加该项目的人最后认为项目中与自省相关的内容非常有用。再结合该分句前的转折连词but可推知，他们一开始对此内容持怀疑态度。2.A。推断。根据第四段的主旨句Databearsout theimportanceofself-reflection可知，该段阐述了自省的重要性，引用theKornFerryInstitute的相关报告是为了支撑主旨句，证明自省的重要性。3.A。理解具体信息。根据第五段内容可知，开启自省之旅的第一步是冥想，而开始冥想的一种方式是放慢生活节奏。也就是说，Carden建议可以从放慢生活节奏开始自省。4.D。理解具体信息。根据倒数第二段中的 She suggested meditating only when somethinghappens that isworth pausingto think about 可知，Carden认为自省不必每天进行，人们只需要在发生了有必要自省的事情时停下来自省。IL.本文是说明文。文章为找兼职工作的学生提供了一些建议。1.E。本段的主要内容是确定自已理想的兼职工作。设空处前提出要通过是否适合自已的学业安排来确定兼职工作，而设空处后的例子是关于做兼职工作的原因，因此，设空处的内容应该是通过自已做兼职工作的原因来确定合适的兼职工作，故E项“想一想你为什么想做兼职工作也是有帮助的”符合语境。E项中的also很好地承接了上文。2.A。设空处是本段的小标题。根据本段中的your own campus is hiring students 以及Campusjobs are the most convenient part-time jobsforyouto get 可知，本段主要是建议学生在自己多次出现的campus形成原词复现关系。3.F。本段主要是建议学生在自已的学校找兼职工作。设空处前的内容表明了校园兼职工作的好处是时间合适，而F项“它们（指校园兼职工作）也是回馈学校的好方法”是关于校园兼职工作的附加好处，符合此处语境。4.G。设空处前指出简历对求职很重要，G项“雇主在见你之前通过它（指简历）了解你”

20、（8分）实验室常用过氧化氢溶液制氧气。实验小组同学对该反应进行探究：实验1：验证二氧化锰是过氧化氢分解的催化剂。0.1g二氧化锰带火星带火星的木条的木条过滤、洗净多次重复1~V过氧化干燥、称量氢溶液IV（1）过氧化氢分解的化学符号表达式为（2）IV中过滤称得的固体质量为g。（3）证明二氧化锰能加快过氧化氢分解速率的实验现象是实验2：探究催化剂种类和质量对H02分解的催化效果的影响。【进行实验】称取催化剂置于三颈瓶中，塞紧橡胶塞，用注射器将3mL5%过氧化氢溶液快速注入，如图过氧化氢完全分解所用时间，实验记录如下氧气浓度传感器催化剂-序号初始温度/℃催化剂种类催化剂质量/g过氧化氢完全分解所用时间/s20二氧化锰0.038②氯化铁200.033220氯化铁0.0429④20氯化铁0.0528【解释与结论】（4）实验2中，效果好的催化剂是（5）实验②③④的目的是（6）继续实验，发现活性炭比二氧化锰的催化效果差。其实验方案：称取0.03g活性炭置于三颈瓶中，塞紧橡胶塞，用注射器将3mL5%过氧化氢溶液快速注入。在初始温度20℃时进行实验，测定结果是（7）通过学，你认为对H02分解催化效果的影响因素应该还有三、计算题(本大题共10分)21. (10分)．如图为某牙膏的部分标签，活性成分单氟磷酸钠的化学式为NaPOF，请回答下列问题：（1）NaPOF的相对分子质量为【主要活性成分】单氟磷酸钠（2）NaPOF中钠元素与氧元素的质量比为）(填最简整数比)。【摩擦剂】碳酸钙（3）若牙膏中其它成分不含氟，则每支这种牙膏中含NaPOF多少克？（写【香型】清爽薄荷出计算过程，结果精确到0.1)【氟含量】0.14%【净含量】200g化学试卷共4页（第4页）

8.通常人们把拆开1mol某化学键所消耗的能量看成该化学键的键能。键能的大小可以衡量化学键的强弱，也可用于估算化学反应的反应热（△H），化学反应的△H等于反应物的总键能与生成物的总键能之差。工业上高纯硅可通过下列反应制取：高温SiCl(g)+2H(g)=Si(s)+4HC1(g），该反应的反应热△H为（）化学键Si-0Si-C1H-HH-CISi——SiSi-C键能/kJ·mol-1460360436431176347A.+412 kJ·mol-1B.-412 kJ·mol-1C.+236 kJ·mol-1D. -236 kJ ·mol-1催化剂9.工业合成三氧化硫的反应为2SO2（g）十O2（g）：2SO;(g)△H=△一198kJ·mol-，反应过程可用如图模拟（代表O2分子，.代表SO2分子，mm代表催化剂),下列说法正确的是（）bIVA.过程I和过程Ⅳ决定了整个反应进行的程度B.过程Ⅱ为放热反应，过程Ⅲ为吸热反应C.1 molSO2和1 molO2反应,放出的热量小于99 kJD.催化剂可降低整个反应的活化能，因此使△H发生变化10.药物异博定(盐酸维拉帕米)能有效控制血压升高、促进血液循环,其合成路线中有如下转化过程：CH3ONaH,DMFOCH3OCHOHXYZ已知:NaH晶体属 NaCl晶型。下列说法正确的是A.Z分子中C原子的杂化类型都是sp²B.Y分子中基态Br原子电子排布式为[Ar]4s²4p0C.X的沸点低于其同分异构体HOD.NaH晶体中，与Na+最近的H-有12个二、非选择题：本题共4小题，共60分。11.(14分)联氨可用作火箭燃料，回答下列问题：(1)火箭推进器中装有肼(N2H4）和过氧化氢，当两者混合时即产生气体，并放出大量的热。已知:N2H4(1)+2H2O2(1)=N2(g)+4H2O(g) △H=-641. 6 kJ·mol-1 ;·0 +=HV ()OH=(DOH【JKT·化学·纠错提分卷（七）第3页（共6页）】

)与浓硝酸反应可CF,),该反应历程中生成两种CF,生成邻硝基三氟甲苯（NO2中间体的能量变化示意图如下。下列说法错误的是能量过渡态1历程1CF3NO2H中间体1过渡态2历程CF3EOKNO,HNOHCF,中间体2+NO反应历程A.生成中间体1、2 的反应均为吸热反应B.反应历程中苯环的大π键没有发生变化CF3C.中间体1是由NO进攻的邻位碳而形成的D.一CF比—CH;更易使苯环上的间位氢原子活化二、非选择题：本题共4小题，共。58分。(1)基态钙原子核外电子的空间运动状态有种，同周期元素中基态原子成对价电子数比钙少的有_（填元素符号）。(2)三聚氰胺是一种重要的工业原料，曾被不法分子作为添加剂而引发毒奶粉事件。三聚氰胺在水中易发生水解和异构化，并与异构化产物形成层状的超分子，部分过程如下：HHNOHNH,HOOH,O异构化H这小中HNH2OHd20甲乙丙(三聚氰胺）①C、N、O第一电离能由大到小的顺序为②甲与丙能够形成层状超分子的原因为乙分子中N原子的孤对电子占据的轨道为（3）由Ca和B两种元素形成晶体的晶胞结构如图（大球代表Ca）①该晶体的化学式为②Ca原子的配位数为跑英交③若晶体的晶胞参数为apm，则该晶体的密度可表示为g·cm-²(设N为阿伏加德罗常数的值）。2025届·普通高中名校联考信息卷（月考四）·化学

)与浓硝酸反应可CF,),该反应历程中生成两种CF,生成邻硝基三氟甲苯（NO2中间体的能量变化示意图如下。下列说法错误的是能量过渡态1历程1CF3NO2H中间体1过渡态2历程CF3EOKNO,HNOHCF,中间体2+NO反应历程A.生成中间体1、2 的反应均为吸热反应B.反应历程中苯环的大π键没有发生变化CF3C.中间体1是由NO进攻的邻位碳而形成的D.一CF比—CH;更易使苯环上的间位氢原子活化二、非选择题：本题共4小题，共。58分。(1)基态钙原子核外电子的空间运动状态有种，同周期元素中基态原子成对价电子数比钙少的有_（填元素符号）。(2)三聚氰胺是一种重要的工业原料，曾被不法分子作为添加剂而引发毒奶粉事件。三聚氰胺在水中易发生水解和异构化，并与异构化产物形成层状的超分子，部分过程如下：HHNOHNH,HOOH,O异构化H这小中HNH2OHd20甲乙丙(三聚氰胺）①C、N、O第一电离能由大到小的顺序为②甲与丙能够形成层状超分子的原因为乙分子中N原子的孤对电子占据的轨道为（3）由Ca和B两种元素形成晶体的晶胞结构如图（大球代表Ca）①该晶体的化学式为②Ca原子的配位数为跑英交③若晶体的晶胞参数为apm，则该晶体的密度可表示为g·cm-²(设N为阿伏加德罗常数的值）。2025届·普通高中名校联考信息卷（月考四）·化学

种不同运动状17.(14 分）铝是应用广泛的金属。以铝土矿（主要成分为AlO，含 SiO、CuO和FeO,等杂质）为原料，判断滴定终点的操作（填字母）。基态Si原子核外共有（5)“电解Ⅱ1"是电解NaCO溶液，原理如图所示。阳极的电极反应式为HO→#装HON（填字母）。（用含b、V的式子表示）。，阴极产生的物质A的化学式为阳离子交换膜（6）以下操作会导致过碳酸钠纯度测定结果偏低的是D.滴定前滴定管尖嘴处有气泡，滴定后气泡消失(3)C、Na、O、Cu的第一电离能由大到小的顺序为_0A.滴定管水洗后未用KMnO标准溶液润洗.摇动锥形瓶时过碳酸钠溶液溅到锥形瓶外V（3）过碳酸钠纯度测定实验的离子方程式为B.锥形瓶用过碳酸钠溶液进行润洗（1）基态AI原子的L层电子排布图为（2）基态Fe原子的核外电子排布式为（5）样品中过碳酸钠的质量分数为制备铝的一种工艺流程如下：铝土矿态的电子。及现象是种空间运动状态充分反应。 反应后向混合物中加人 NaCI 固体,搅拌、静置、过滤、洗涤、低温干燥,得到过碳酸钠固体。取 25. 00 mL 溶液于锥形瓶,加人足量稀硫酸,用 0. 0400 mol L-1的 KMnO,标准溶液滴定至终点,加人NaCI固体的（填元素符号）。（填字母）。15. (15 分)为揭示原子结构的奥秘,科学家经历了浸长的探索。 回答下列问题：【高二上学期期末联考试卷·化学第4页（共6页）】_个原子轨道，其中能级较高的轨道形状为B.1s²2s²2p3d²D. 1s²2s2p²称取b g 2NaCO,·3HzO(M=314 g·mol-1)配成 100 mL 溶液。(2)下图为“溶液配制”的部分过程，操作 a 应重复 3 次，目的是（4）下列属于氟原子激发态的电子排布式且能量较高的是操作a个电子，有（1)反应过程中要控制温度不要太高的原因是二、非选择题:本题共 4 小题,共 58 分。 （填“s”或“p”）区。钠并测定其纯度的步骤如下：不同的电子，最外层有Ⅱ. 过碳酸钠溶液的配制消耗KMnO标准溶液VmL。大I.过碳酸钠的合成Ⅲ.过碳酸钠纯度测定A.1s²2s²2p3sC.1s²2s²2p²3p²(1)L层共有回答下列问题：作用是