学生用人书名师导学·选择性考试第一轮总复·化学第6章物质结构与性质考点集训（十四）原子结构与性质6.(教材改编)已知某元素十3价离子的电子排[A组]布式为1s22s22p3s23p3d5,该元素在周期一、选择题（每小题只有一个选项符合题意）表中的位置是1.(教材改编)主族元素的基态原子，M层上有A第三周期第Ⅷ族，p区一个半充满的能级，该原子的质子数B.第四周期第Ⅷ族，d区A.只能是7B.只能是15C.第三周期第VB族，ds区C.是11或13D.是11或15D.第四周期第VB族，f区2.(教材改编)下列各原子或离子的电子排布7.(教材改编)下列说法不正确的是式错误的是A.所有区的名称均来自按构造原理最后填A.K+1s22s22p53s23p人电子的能级符号B.As 1s22s22p3s23p63d104s24p3B.在1~6周期中，周期序数越大，该周期所C.N3-1s22s22p含金属元素越多D.Ca 1s22s22p3s23p3d2C.元素原子的核外电子排布呈现周期性变3.（教材改编)下列各项中，前面的能级先填入化是形成元素周期律的根本原因电子的是D.周期表共18个纵列，可分为7个主族，7①3d和4s②4p和5s③5s和4d个副族，1个Ⅷ族，1个0族④5p和4d8.已知X、Y元素同周期，且电负性X>Y,下A.①②B.②③列说法错误的是A第一电离能Y可能大于XC.②④D.③④4.(教材改编)下列微粒中，未成对电子数最多B.简单气态氢化物的稳定性：HY大的是于HnXA.C:1s22s22p2C.最高价含氧酸的酸性：X可能强于YB.S:1s22s22p63s23p4D.X和Y形成化合物时，X显负价，Y显C.Cr:1s22s22p63s23p53d54sl正价D.Fe:1s22s22p53s23p53d54s29.(2022·湖北联考)“中国天眼”探测到距离地球79光年的恒星光谱，经光谱分析该恒5.(教材改编)下列电子排布式（图）中，原子不星的组成元素有硅、磷、铁、硫等。下列说法是处于激发状态的是错误的是A氮原子口A.硅位于元素周期表的p区B.氟原子：1s22s22p3sB.基态磷原子的未成对电子数为3C.锰原子：[Ar3d54s2C.基态铁原子的电子排布式为[Kr]3d4s2D.铜原子：1s22s22p3s23p3d94s2D.硫的第一电离能小于磷的第一电离能430

二、非选择题：本大题共5小题，共52分。17.阅读材料，完成下列要求。(8分)实现高质量发展是中国式现代化的本质要求之一，是全面建设社会主义现代化国家的首要任务。广东肩负着在推进中国式现代化建设中走在前列的重大使命任务。广东全省锚定高质量发展的首要任务，共同为“再造一个新广东、再创让世界刮目相看的新奇迹”努力奋斗。一是当好中国制造业发展的排头兵，深入实施“广东强芯”工程，聚力走好科技自立自强之路，夯实实体经济基础；二是加快推动产业集群化发展，培育十大战略性支柱和十大新兴产业集群，使其成为全省经济高质量发展的中流砥柱；三是做实做强新发展格局，拓宽内外通道，链接全球市场，激活新动能，注入新活力；四是加强高质量发展政策供给，进一步优化营商环境，精准扶持经营主体，提振企业信心，助力企业发展。站在新的历史起，点上，广东将不断保持“闯”的精神、“剑”的劲头、“干”的作风，努力续写更多“春天的故事”，踏实走好中国式现代化的广东路径。结合材料，运用《经济与社会》知识，分析说明应如何实现中国式现代化的广东路径。18.阅读材料，完成下列要求。（7分)我国在全球公共安全合作论坛2023年大会上再次提出全球安全倡仪、全球发展倡议，倡议指出：和、发展、合作、共赢的历史潮流不可阻挡，但和赤字、发展赤字、安全赤字、治理赤字加重。面对全球性的公共安全威胁，唯有团结合作才是人间正道。中方坚持共同、综合、合作、可持续的安全观，倡导走出一条对话而不对抗、结伴而不结盟、共赢而非零和的新型安全之路。中方重视各国合理安全关切，推动国际社会以团结精神和共赢理念应对复杂多变的安全挑战。各国需要加强合作，深化彼此互信，不干涉别国内政。同时，也要密切协调制定新规则、法律等，以应对全球不断涌现的新挑战，“一带一路”倡议能够为参与国家带来安全与发展。运用世界多极化的知识，阐述我国提出的全球安全倡议、全球发展倡议对于世界和与发展具有怎样的意义。19.阅读材料，完成下列要求。(8分)雷大姐连续两届担任全国人大代表，日里经常挨家挨户走访，倾听群众心声。许多群众反映，想加强对政策理论和农业技术的学，增强致富的本领。过去，雷大姐所在社区卫生环境脏乱差，基础设施薄弱破旧，她想方设法改善社区人居环境，提升群众幸福指数。她先后提出关于全面推进乡村振兴的建议50余件，受到有关部门的高度重视。在十三届全国人大四次会议上，她递交了关于加大支持农村人居环境整治工作资金投入的建议，受到财政部的重视。她还提出了关于发展黄河流域旱作高效农业的建议，得到农业农村部致函回复和重视。谈起履职感受时，她说：“作为一名人大代表，我始终和群众在一起，全过程参与民主选举、民主协商、民主决策、民主管理、民主监督，把群众心声转化为意见建议，把群众期盼变为现实。”结合材料，运用《政治与法治》知识，说明全国人大代表是如何“把群众期盼变为现实”的。【高三思想政治第5页（共6页）】·24-35C·

L图，在四棱锥P-ABCD中，PC⊥底面ABCD,底面ABCD是直角形ABLAD.AB/CD.AB=2AD=2CD2,E是PB上的.点QD求证：面EAC⊥面PBC,2)若PC=2.二面角PACE的余弦值为，求直线PA与面EAC所成角的正弦值。能顺02分)尼知椭圆C号+-1>60经过点3，》其右焦点为F30)检的()求椭圆C的标准方程；0名述指〔2)椭圆C的右顶点为A,若点P,Q在椭圆C上，且满足直线AP与AQ的斜率之积为0，求△APQ个环面积的最大值.计算73.2(12分)设向量m=(anx,号)n=(1,z2),fx)=m·n-(a+1)x,a∈R.(1)讨论函数f(x)的单调性；（2)设面数g)-2)-十2a十，者8)存在两个极值点2(a-2)(x1-x2).【名校之约系列2023高考考前冲刺押题卷（三）·数学第4页（共4页)】

第二节（共5小题：每小题2分，满分10分）根据短文内容，从短文后的选项中选出能填人空白处的最佳选项。选项中有两项为多余选项。Basketball is a great sport that is not only fun,but also brings children many benefits n differentways.36LPlaying basketball has physical benefits.Children are full of energy-they need to move,jump andunconstantly.Basketball will allow them to conro that energy in a positive way.It'safull-bodysport.3f）Since it's a fast and dynamic sport,children need tofollow the game and the continuous movementof the ball.The ball moves quickly from one side of the court to the other and the kids move at the samepace which helps improve both resistance and speed.Playing basketball has cognitive()benefits.Children who practice playing basketball developskills that help them fight against opponents and move around the court.This sport helps them increasetheir ability to concentrate.Children will learn to judge surrounding situations and problems thatmay arise,and then find the best and fastest solution.Since it's a team sport,basketball promotes sociability,co-existence and respect among peers.It's ideal for shy children because they will have to learn to interact with other players.This is importantboth to get better at the sport and to have more fun.These are not all of the advantages of playing basketball.The most important thing is that it'sa very fast and fun sport.This tends to make the vast majority of children enjoy it.A.In fact,there are many other benefitsB.It helps children o better in their school performance.C.Playing basketball has social and emotional advantagesD.This means that it strengthens muscles in their whole bodyE.It also makes them more aware of the envirorment around them.F.This spory promotes healthy development in children for a number of reasons.G.However,there are some disadvantages when children keep running on the court.第三部分语言知识运用（共两节，满分45分）第一节（共20小题；每小题1.5分，满分30分）阅读下面短文，从短文后各题所给的A、B、C和D四个选项中，选出可以填入空白处的最佳选项I met an old friend today whom I've known since childhood,and we went for a drive.I could immediately find that he was very 41.I didn't mean wealth by economic standards,but I could see an 42around him that reflected the joy,happiness,comfort,and peace that filled his very being.He didn't havemuch to 43,but I could tell he was in deep thought and this 44 told me a lot.He told me aboutmany things that he no longer took for granted.He 45 with me how fortunate he was to recognizewhat he had that he never46 before..理ir当级，I wasn't surprised,as I continued to 47 him.After all,he had so much and he had taken his situation in life simply as his reward for being good.Hetold me how 48 he was to have had parents,whoraised him,fed him,clothed him,and 49 loved him thou his growng years.He tod me abou hisfather who had did shorly er hisfrom wrkand that his mother had ivdlife.beHe spoke of his family and how51 he was of his wife,his children and his grandchildren.Hespoke of the grete love of the entire5 and how they all ejoyed gtering fo bithdays and holidays.He had great 53 of the achievements of his familyHis wife had designed and built their home.His children had families and jobs they 54 going toeach day.There was55 in eac family.However,he beame upset with56s he discussed the空、卷()第2页【21·DY·英语R一英语5一Y)

阅读》高三⑧)eading)NGLISH￥美程第3期tourists总19044角may主管单植山西省教育厅主办单位山西教育教辅传媒集团编辑出版学英语报社社长昌夺明总编李若广编审N6 cy E Rley国内统一刊号CN14072C2021年7月20日星期二http:/Awww..com单元知识点复(Unit3,Module1)OLLECTIONSCHECKING CORNER共55分L1001二1高三版)重点单词用括号内所给单词的适当形式填空。（每小题2.即使大卫知道这项任备很难完或，他色毫不1分，共10分)统豫地接受了(emf的这步录语从句)1.graduate v./n.n.毕业人”根本任务1.Expecting to work in Silicon Valley after his2.occasion n.ad山.偶尔的，，偶然(graduate),Wang is willing to mix3.在那一地区得列好的教育很难shed核心素养的→ad.偶尔地，不时地the two cultures to form his own values.to do)看写“综合语3.tradition n.→a.传统的→2.Paper-cutting is an important part ofad.传统地(tradition)Chinese culture.4.人们认为有规常戴体的人很少海冒，t以4.celebrate v.n.庆祝，庆典3.During the Spring Festival,there are nationalbelieved that..)课标、新课5.power v./nad山.强大的，有力的(celebrate)with feasts and fireworks.5.婚华通常用丝号和花来装佛bedc的逐步落实，ad心.无力的，无能的4.The family were looking for Rose,but did not see对学生基础(dark).动)6.dark n./adj.→.黑暗，漆黑her as she was lying in tota英语阅读量y.使变暗，使变黑5.When I expressed my(congratulate)toV,用适当的情态动国或括号内动词的适当形式填空（每小题1分，共10分）合运用能力7.destroy v,→adj.毁灭性的her,Anna only smiled at me.climb的要求。在n,破坏，摧毁6.Miss Yang received the(invite)to the1.The lift was out of order,soa山装饰的，作装饰film festival,but she refused.the stairs.《学英语》8.decorate v.n,装饰，装饰品7.Dr.Tedros has also blamed some countries for2.Susan has a great giftfor ms and she报》英文版用的(serous)9hoil v./n.a山热的，沸腾的failing to take the outbreakplay the piano and violin.3.Bob has gone to France for his holiday,soarty thi

22.Which is suitable for a teenager with a sense of adventure?A.Ireland:Beauty and a Long History of SeparationB.Swiss Family Adventure:An Active Journey Through the AlpsC.Climate Change in New Orleans:A meeting and observationD.Active Argentina and Patagonia23.Who may be interested in the journey to Argentina?A.Writers.B.Historians.C.Environment specialists.D.Sports lovers.BIt was a very hot day in late summer.I was a young dad working in a local wood mill.It wasdangerous,back-breaking work that paid very little.In the year I had worked there,only four otherpeople hadn't quit and been replaced with new faces.Those of us who stayed did so only becausethere was no other work to find to support our families.On this day the fans weren't working and alt of us were covered in sweat and sawdust.When Ilooked around every face I saw looked angry and frustrated.Suddenly,a voice called out:"Hey!There's a deer in here."A lost little doe()had wandered through the open loading bay doorsand was now cowering()in between the huge stacks of wood.All of us stopped working andwent looking for her as she ran about looking for a way out.Now most people where I live hunt deer for meat in the fall,but also treat them with greatkindness the rest of the year.Many will even buy 50lb bags of corn to help feed them during theharsh winter months.It was no surprise then that all of us were soon quickly working together tofree this little doe.By blocking off all the other routes we were able to guide her panic search back tothe open bay doors.We watched as she jumped out of the building and back into the woods.Then wewalked back in to work.I noticed something,though.On every face there was a joyful smile.It wasas if this one single act of kindness had energized us again and reminded us of what life is all about.24.Why did people still work in the local wood mill?A.They could earn high income.B.They were satisfied with the boss.C.The conditions were not so bad.benferredaccrdD.They had no choice of other work.A.The workers wasn't surprised to see a deer.B.Workers wanted to help the deer out of their working place.C.The deer was trapped in a big well.D.The deer entered the mill on purpose.26.In what way did workers free the deer?A.By instructing her to the right way.B.By inducing the deer with corn.C.By using familiar signals.D.By blocking all the doors of the mill.27.The following words can best describe the workers exceptA.kind-heartedB.lovingC.hard workingD.enthusiasticAndean Condors(),weighing up to 13 kilograms with a 10-foot wingspan,are one of theworld's heaviest and largest flying birds.Spending their days circling the Andes mountains and nearby Pacific coasts in search of food,they manage to stay afloat()for hours.Though researchers have long suspected that the massive creatures conserved energy by usingrising air currents to surf the skies,nobody had ever documented how infrequently the birds usedtheir wings afloat.Now,a new study has found that the incredibly energy-efficient condors use theirwings just 1 percent of their time-mostly during takeoff and landing.The extensive research,conducted in Patagonia from 2013 to 2018,involved attaching high-tech flight re-corders to the birds'wings.The collected information was too much to send back via the phone or satellite net-work.Hence,the researchers had to physically take back the devices,which were designed to fall off the birdsafter a week.While a GPS tracker allowed the scientists to confirm the recorders'exact locations,getting tothem was no easy task given Patagonia's rough surface features.itsAfter losing seven recorders for every one they took back,the team shifted their focus to youn-ger condors.who tend to fly over gently rolling hills rather than the mountain tops frequented by a-dults.The 250 hours of collected flight data revealed that the birds flew for an average of three hoursbut flapped()their wings for less than two minutes of the time.Oe efficient pilot managed to cover 172 kilometers over five hours without a single flap!The researcherssay the large fliers consume the most energy during takeoff.However,once in the air,they can fly for long periods of time without turning on their"engines"The scientists suppose that adult condors may demonstrateneven more impressive flight record than the younger.S2名师原创模拟八·英语第3页（共6页）

■口口■口口■第二节（满分25分）【参考范文】Paragraph 1:When they pulled up less than ten minutes later,the emergency workers were treatingPhillips.The quick response from Julia and Charlie saved Ann's life.She arrived at the hospital intime to get treatment and before chronic damage occurred."If it weren't for them,I wouldn't behere,"said Ann from her hospital bed about a month after her stroke.Thanks to an extended stay inthe hospital,she has regained most of the movement throughout her body except for one hand and aportion of her mouth,which affects her speech."I'm proud that people responded so quickly that itdid make a difference for Mrs.Phillips,says Julia."I am so pleased to be part of such a caringcommunity.”Paragraph 2:But the school's crisis response is only one piece of the community's extraordinaryefforts.Another family with young children took in the two girls.When that became too much tohandle during the day with at-home learning,school contacted the local Boys and Girls Club,wherethe girls now spend their days as part of a program to help working parents.They return to the hostfamily at night.Virtual learning has been a challenge across the country,but in Muskegon Heights ithas helped the community grow closer.Many teachers there gave their personal phone numbers tostudents and families in case they needed extra help.In this case,the exchange is literallylife-altering,for people care about each other,and they don't just say the words.They just followthrough.【解析】第二部分阅读第一节A【语篇导读】A篇是一篇应用文。介绍了四个不太知名的国家公园。2l.B由Buffalo National River Park所在段落的倒数第二行“Those visitors thatwant to try other activities can enjoy horseback riding,fishing,..."答案为B。英语参考答案·第2页（共9页）

efforts into dealing with a much bigger global polluter:the fashion industry.Usng thepe ofrcu her company has developedamugetotuclthngfbesitoo-based pasic Thispcthen be used by manufacturers(制造商）in theirexisting machines,s that yourirtsd jeasreused asbrad-ew products.wanted to take the fibresadthem into something that would be used for many years to come,Bassi says.With the rise n limatechange activism,any fashion brands face exter pressetheirat,and Kleiderly has had interefom ktoreythei8.What is paragraph 1 mainly about?A.The harm of over-consumption.B.The fast-changing fashion trends.C.The new way of waste treatment.D.The huge waste in the fashion industry.29.What do we know about Bassi's first job?12A.It went against her personal values.B.It drew her attention to climate change.C.It inspired her to make a film about environment.D.It enabled her to effect a change in the oil industry.30.What is the aim of Kleiderly?A.To create clothes meant to last.B.To lower the carbon impact of fashion.C.To use abandoned clothes to make oil.D.To reduce oil-based plastic in clothing making.What is of KidyA.It will update manufacturers'machinesB.It will face great external pressure.C.It will do business with many fashion brands.D.It will put an end to climate change activism.DThe outermost layer of the sun,called the corona),is extraordinarily difficult tostudy,but now researchers have made the first map of its magnetic field (This willhelp us predict solar fires that potentially threaten the Earth.The plasmaa hot,ionised(state of matterthat makes up theisiredyuncertain which is why it isn't visibe with the aked veexcetduringtoelipse(Thtnertinty,ngwith the brightes of the dikof theit tough to measure.Stevenat theUSNc Colorad and hiscollegedMchPrmeblock out the ih from the sunin itThallowed thetetrThy theefavethat move through the corona like ripples on the oceanpfewdensity and the magnetic field strengths,so those measurements allowed the researchers tocalculate the magnetic field strength across the corona.They found it was between 1 and 4gauss,which is more than 10 times weaker than the magnetic field of a typical refrigeratomagnet.e are very small magnetic fields,but they're important,"says Tomezyk.magneteege wiatednytewhiccanbimpactful to the Earthtosatellites,GPS systems,nd【高三第五次联考·英语第5页（共8页）Q©

山西省2023年中考总复预测模拟卷数学（五）题、号三总分得分注意事项：1.本试卷分第I卷和第Ⅱ卷两部分，全卷共8页，满分120分，考试时间120分钟。2.答卷前，考生务必将自己的姓名、准考证号写在本试卷相应的位置.樊第I卷选择题（共30分）细评卷人一、选择题（本大题共10个小题，每小题3分，共30分，在每个小题得分·02是给出的四个选项中，只有一项符合题目要求)1.√9的相反数是:破急治.娶梦批（降食言数(BA.9B.-3C.30D.-3数2.日常生活中，人们常用“一刹那”这个词来形容时间极为短暂.“一刹那”是古代印度的个时间单位，如果与现代时间（一昼夜为24小时）对比，“一刹那”只有0.000005小时，该8数据可以用科学计数法表示为(BA.0.5×10-5小时B.5×10-6小时别C:一5x10小时帕食08千谢不藏宏，D.-0.5×105小时南3.太原市一彩民购买了一张彩票，并且中奖了，这个事件是A.必然事件B.确定性事件C.不可能事件D.随机事件(6向4.下列各式中，计算结果等于a7的是0”参A尘学羊一干素A:a'taB.a8-a拉预项时中学C.a4a2学四T(DD.a2.a图2x-6>0,翻5.不等式组的解集是4-x5B.3y2>y3D.y3>y1>y2SX数学预测模拟卷（五）第1页共8页

只(12分)设数列a的前n项和为5,3.=2a十2-6(n∈N).(1)求数列{a,的通项公式学华高普680(2)若数列2+1258,求m的值.anan+】的前m项和T。:枣意20.(12分)如图，正方体ABCD-ABCD的棱长为4，点E,P分别是DD1、A,C的中点(1)求证：BP⊥面AEC;D(2)求直线B,C与面A,EC所成角的正弦值B但及个一月只，中法个四的出登小日者公讲共，公小岳，限水21.(12分)已知双曲线C号一芳-1(a>0.b>0)的一条渐近线方程为1一2y=0,一个焦点到该渐近线的距离为1.(1)求双曲线C的方程；(2)若双曲线C的右顶点为A,直线：y-kx+m与双曲线C相交于M,N两点(M,N不是左右顶点)，且AM·A下=0.求证：直线1过定点，并求出该定点的坐标22.(12分)已知函数f(x)=e十x十4n(2-x).(1)求函数fx)的图象在(0，f0)处的切线方程；(2)判断函数f(x)的零点个数，并说明理由.的进爱诗的雅陆大有余的向00一。2=小。且4是向家分【2023仿真模拟卷·数学（四）第4页（共4页）】新高考